Article,
Oxygen tri-clusters make glass highly crack-resistant
Affiliations
- [1] Shanghai Institute of Optics and Fine Mechanics [NORA names: China; Asia, East];
- [2] Aalborg University [NORA names: AAU Aalborg University; University; Denmark; Europe, EU; Nordic; OECD]
Abstract
Identifying key structural factors that surmount their intrinsic brittleness and poor crack initiation resistance (C) is crucial for designing glass efficiently and predictably. In this study, we present three significant discoveries that contribute to the design of glasses with superior mechanical performances. Firstly, the C of the aluminosilicate glasses exhibited a drastic increase when the alumina content surpasses a critical threshold. Secondly, the fraction of three-coordinated oxygens (i.e., oxygen tri-cluster fraction [O]) was successfully quantified using our new Nuclear Magnetic Resonance technique. Thirdly, a correlation between the evolution trend of the [O] and the alumina content was established, which aligns closely with the C trend. These findings suggest that oxygen tri-clusters play a crucial role in significantly enhancing C in aluminosilicate glasses.